(ppy)2Ir(acac)及(btp)2Ir(acac)製程精進

功能性化學品關鍵技術開發與應用四年計畫

完成(ppy)2Ir(acac)及(btp)2Ir(acac)製程及精進研究，掌握最佳製程操作條件。其中(ppy)2Ir(acac)製程採High mole ratio方式，Dimer部分母液回收使用提高效益 (4批反應總mole  ratio為4.2，總粗產率高達95%，總反應時間由96hrs縮短為16.3hrs)；最終成品部分以30%MeONa取代Na2CO3，粗產率由50%提高至100%，反應時間可縮短一半

Complete (ppy) 2Ir (acac) and (btp) 2Ir (acac) process and sophisticated research, master the best process operating conditions. ( the total molar ratio of 4 batchs reactions was 4.2, the total yield of up to 95%, the total reaction time from 96hrs shortened to 16.3hrs). The final finished part of the 30% MeONa to replace Na2CO3, crude yield was from 50% to 100%, the reaction time can be reduced by half.